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Publications:  Prof Antonin Vlcek

Pižl M, Hunter BM, Greetham GM et al.(2017). Ultrafast Wiggling and Jiggling: Ir2(1,8-diisocyanomenthane)42. J Phys Chem A vol. 121, (48) 9275-9283.
Záliš S, Hunter BM, Gray HB et al.(2017). Electronic Structures of Reduced and Superreduced Ir2(1,8-diisocyanomenthane)4n+ Complexes. Inorg Chem vol. 56, (5) 2874-2883.
Monni R, Auböck G, Kinschel D et al.(2017). Conservation of vibrational coherence in ultrafast electronic relaxation: The case of diplatinum complexes in solution. Chemical Physics Letters vol. 683, 112-120.
Gray HB, Záliš S, Vl¿ek A(2017). Electronic structures and photophysics of d<sup>8</sup>-d<sup>8</sup> complexes. Coordination Chemistry Reviews
Darnton TV, Hunter BM, Hill MG et al.(2016). Reduced and Superreduced Diplatinum Complexes. J Am Chem Soc vol. 138, (17) 5699-5705.
Hofbeck T, Lam YC, Kalbá¿ M et al.(2016). Thermally Tunable Dual Emission of the d(8)-d(8) Dimer [Pt2(μ-P2O5(BF2)2)4](4). Inorg Chem vol. 55, (5) 2441-2449.
Kvapilová H, Vl¿ek A, Barone V et al.(2015). Anharmonicity Effects in IR Spectra of [Re(X)(CO)3(α-diimine)] (α-diimine = 2,2'-bipyridine or pyridylimidazo[1,5-a]pyridine; X = Cl or NCS) Complexes in Ground and Excited Electronic States. J Phys Chem A vol. 119, (40) 10137-10146.
Kvapilová H, Sattler W, Sattler A et al.(2015). Electronic Excited States of Tungsten(0) Arylisocyanides. Inorg Chem vol. 54, (17) 8518-8528.
McCusker JK, Vl¿ek A(2015). Ultrafast excited-state processes in inorganic systems. Acc Chem Res vol. 48, (5) 1207-1208.
Záliš S, Lam Y-C, Gray HB et al.(2015). Spin-orbit TDDFT electronic structure of diplatinum(II,II) complexes. Inorg Chem vol. 54, (7) 3491-3500.
Vl¿ek A, Kvapilová H, Towrie M et al.(2015). Electron-transfer acceleration investigated by time resolved infrared spectroscopy. Acc Chem Res vol. 48, (3) 868-876.
Ceroni P, Pikramenou Z, Prodi L et al.(2015). Luminescence sensing and imaging: general discussion. Faraday Discuss vol. 185, 311-335.
Bohne C, Pan Q, Ceroni P et al.(2015). Natural and artificial photosynthesis: general discussion. Faraday Discuss vol. 185, 187-217.
Frei F, Rondi A, Espa D et al.(2014). Ultrafast electronic and vibrational relaxations in mixed-ligand dithione-dithiolato Ni, Pd, and Pt complexes. Dalton Trans vol. 43, (47) 17666-17676.
Pospíšil P, Luxem KE, Ener M et al.(2014). Fluorescence quenching of (dimethylamino)naphthalene dyes Badan and Prodan by tryptophan in cytochromes P450 and micelles. J Phys Chem B vol. 118, (34) 10085-10091.
Blanco-Rodríguez AM, Kvapilová H, Sýkora J et al.(2014). Photophysics of singlet and triplet intraligand excited states in [ReCl(CO)3(1-(2-pyridyl)-imidazo[1,5-α]pyridine)] complexes. J Am Chem Soc vol. 136, (16) 5963-5973.
Takematsu K, Williamson H, Winkler JR et al. (2014). Intra- and intermolecular electron hopping via tryptophan in azurin. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY. vol. 19, S231-S231.
Zeng Q, Messaoudani M, Jr VA et al.(2013). Temperature-dependent reduction pathways of complexes fac-[Re(CO)(3)(N-R-imidazole)(1,10-phenanthroline)(+) (R = H, CH3). ELECTROCHIMICA ACTA vol. 110, 702-708.
Takematsu K, Williamson H, Blanco-Rodríguez AM et al.(2013). Tryptophan-accelerated electron flow across a protein-protein interface. J Am Chem Soc vol. 135, (41) 15515-15525.
Perutz RN, Torres O, Vl¿ek A(2013). Photochemistry of Metal Carbonyls. Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications, vol. 8,
Záliš S, Milne CJ, El Nahhas A et al.(2013). Re and Br X-ray absorption near-edge structure study of the ground and excited states of [ReBr(CO)3(bpy)] interpreted by DFT and TD-DFT calculations. Inorg Chem vol. 52, (10) 5775-5785.
El Nahhas A, van der Veen RM, Penfold TJ et al.(2013). X-ray absorption spectroscopy of ground and excited rhenium-carbonyl-diimine complexes: evidence for a two-center electron transfer. J Phys Chem A vol. 117, (2) 361-369.
Perutz RN, Torres O, Vl¿ek A(2013). Photochemistry of Metal Carbonyls. Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications, vol. 8,
Heydová R, Gindensperger E, Romano R et al.(2012). Spin-orbit treatment of UV-vis absorption spectra and photophysics of rhenium(I) carbonyl-bipyridine complexes: MS-CASPT2 and TD-DFT analysis. J Phys Chem A vol. 116, (46) 11319-11329.
Warren JJ, Ener ME, Jr VA et al.(2012). Electron hopping through proteins. COORDINATION CHEMISTRY REVIEWS vol. 256, (21-22) 2478-2487.
Jr VA(2012). Solar fuels Preface. COORDINATION CHEMISTRY REVIEWS vol. 256, (21-22) 2397-2398.
Durrell AC, Keller GE, Lam Y-C et al.(2012). Structural control of 1A2u-to-3A2u intersystem crossing in diplatinum(II,II) complexes. J Am Chem Soc vol. 134, (34) 14201-14207.
Zeng Q, Messaoudani M, Jr VA et al.(2012). Electrochemical Reductive Deprotonation of an Imidazole Ligand in a Bipyridine Tricarbonyl Rhenium(I) Complex. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (3) 471-474.
Olmon ED, Sontz PA, Blanco-Rodríguez AM et al.(2011). Charge photoinjection in intercalated and covalently bound [Re(CO)3(dppz)(py)]+-DNA constructs monitored by time-resolved visible and infrared spectroscopy. J Am Chem Soc vol. 133, (34) 13718-13730.
Zalis S, Consani C, El Nahhas A et al.(2011). Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2 '-bipyridine and 1,10-phenanthroline complexes. INORG CHIM ACTA vol. 374, (1) 578-585.
Blanco-Rodríguez AM, Towrie M, Sýkora J et al.(2011). Photoinduced intramolecular tryptophan oxidation and excited-state behavior of [Re(L-AA)(CO)3(α-diimine)](+) (L = pyridine or imidazole, AA = tryptophan, tyrosine, phenylalanine). Inorg Chem vol. 50, (13) 6122-6134.
Blanco-Rodríguez AM, Di Bilio AJ, Shih C et al.(2011). Phototriggering electron flow through Re(I)-modified Pseudomonas aeruginosa azurins. Chemistry vol. 17, (19) 5350-5361.
Sokolová L, Williamson H, Sýkora J et al.(2011). Mass spectrometric characterization of oligomers in Pseudomonas aeruginosa azurin solutions. J Phys Chem B vol. 115, (16) 4790-4800.
El Nahhas A, Consani C, Blanco-Rodríguez AM et al.(2011). Ultrafast excited-state dynamics of rhenium(I) photosensitizers [Re(Cl)(CO)3(N,N)] and [Re(imidazole)(CO)3(N,N)]+: diimine effects. Inorg Chem vol. 50, (7) 2932-2943.
Bakova R, Chergui M, Daniel C et al.(2011). Relativistic effects in spectroscopy and photophysics of heavy-metal complexes illustrated by spin-orbit calculations of [Re(imidazole)(CO)(3)(phen)](+). COORDIN CHEM REV vol. 255, (7-8) 975-989.
van der Veen RM, Cannizzo A, van Mourik F et al.(2011). Vibrational relaxation and intersystem crossing of binuclear metal complexes in solution. J Am Chem Soc vol. 133, (2) 305-315.
Williamson HR, Sokolova L, Sykora J et al.(2010). Kinetics of electron transfer in Re(H126)(W122) Pseudomonas aeruginosa azurin. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY vol. 240,
Vlcek A(2010). Dithiolenes and non-innocent redox-active ligands Preface. COORDIN CHEM REV vol. 254, (13-14) 1357-1357.
El Nahhas A, Cannizzo A, van Mourik F et al.(2010). Ultrafast excited-state dynamics of [Re(L)(CO)3(bpy)]n complexes: involvement of the solvent. J Phys Chem A vol. 114, (22) 6361-6369.
Vlcek A(2010). Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry. TOP ORGANOMETAL CHEM vol. 29, 73-114.
Blanco-Rodríguez AM, Busby M, Ronayne K et al.(2009). Relaxation dynamics of Pseudomonas aeruginosa Re(I)(CO)3(alpha-diimine)(HisX)+ (X = 83, 107, 109, 124, 126)Cu(II) azurins. J Am Chem Soc vol. 131, (33) 11788-11800.
Blanco-Rodriguez AM, Towrie M, Collin JP et al.(2009). Excited-state relaxation dynamics of Re(I) tricarbonyl complexes with macrocyclic phenanthroline ligands studied by time-resolved IR spectroscopy. DALTON T (20) 3941-3949.
Messmer A, Rodriguez AMB, Sebera J et al. (2009). How do vibrations change their composition upon electronic excitation? - EXSY-T2D-IR measurements challenge DFT calculations. ULTRAFAST PHENOMENA XVI. Editors: Corkum, P, DeSilvestri, S, Nelson, KA, Riedle, E et al., vol. 92, 421-423.
Cannizzo A, Blanco-Rodriguez AM, El Nahhas A et al.(2008). Femtosecond fluorescence and intersystem crossing in rhenium(I) carbonyl-bipyridine complexes. J AM CHEM SOC vol. 130, (28) 8967-8974.
Shih C, Museth AK, Abrahamsson M et al.(2008). Tryptophan-accelerated electron flow through proteins. SCIENCE vol. 320, (5884) 1760-1762.
Gabrielsson A, Towrie M, Zális S et al.(2008). Nanosecond CO photodissociation and excited-state character of [Ru(X)(X')(CO)2(N,N'-diisopropyl-1,4-diazabutadiene)] (X=X'=Cl or I; X=Me, X'=I; X=SnPh3, X'=Cl) studied by time-resolved infrared spectroscopy and DFT calculations. Inorg Chem vol. 47, (10) 4236-4242.
Blanco-Rodriguez AM, Ronayne KL, Zalis S et al.(2008). Solvation-driven excited-state dynamics of [Re(4-Et-Pyridine)(CO)(3)(2,2 '-bipyridine)](+) in imidazolium ionic liquids. A time-resolved infrared and phosphorescence study. J PHYS CHEM A vol. 112, (16) 3506-3514.
Busby M, Hartl F, Matousek P et al.(2008). Ultrafast excited state dynamics controlling photochemical isomerization of N-methyl-4-[trans-2-(4-pyridyl)ethenyl]pyridinium coordinated to a {Re I(CO)3(2,2'-bipyridine)} chromophore. Chemistry vol. 14, (23) 6912-6923.
Sato S, Sekine A, Ohashi Y et al.(2007). Photochemical ligand substitution reactions of fac-[Re(bpy)(CO)3Cl] and derivatives. Inorg Chem vol. 46, (9) 3531-3540.
Busby M, Matousek P, Towrie M et al.(2007). Ultrafast excited-state dynamics of photoisomerizing complexes fac-[Re(Cl)(CO)(3)(papy)(2)] and fac-[Re(papy)(CO)(3)(bpy)](+) (papy = trans-4-phenylazopyridine). INORG CHIM ACTA vol. 360, (3) 885-896.
Vlcek A, Zalis S(2007). Modeling of charge-transfer transitions and excited states in d(6) transition metal complexes by DFT techniques. COORDIN CHEM REV vol. 251, (3-4) 258-287.
Gabrielsson A, Busby M, Matousek P et al.(2006). Electronic structure and excited states of rhenium(I) amido and phosphido carbonyl-bipyridine complexes studied by picosecond time-resolved IR spectroscopy and DFT calculations. Inorg Chem vol. 45, (24) 9789-9797.
Vlcek A, Busby M (2006). Ultrafast ligand-to-ligand electron and energy transfer in the complexes fac-[Re-I(L)(CO)(3)(bpy)](n+). COORDINATION CHEMISTRY REVIEWS. vol. 250, 1755-1762.
Gabrielsson A, Blanco-Rodriguez AM, Matousek P et al.(2006). Different mechanisms of photochemical Re-Me and Re-Et bond homolysis in [Re(R)(CO)(3)(4,4 '-dimethyl-2,2 '-bipyridine)]. A time-resolved IR spectroscopic study ranging from picoseconds to microseconds. ORGANOMETALLICS vol. 25, (9) 2148-2156.
Blanco-Rodriguez AM, Busby M, Gradinaru C et al.(2006). Excited-state dynamics of structurally characterized [Re-I(CO)(3)(phen)(HisX)](+) (X=83,109) Pseudomonas aeruginosa azurins in aqueous solution. J AM CHEM SOC vol. 128, (13) 4365-4370.
Gabrielsson A, Hartl F, Zhang H et al.(2006). Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy. J Am Chem Soc vol. 128, (13) 4253-4266.
Gabrielsson A, Matousek P, Towrie M et al.(2005). Excited states of nitro-polypyridine metal complexes and their ultrafast decay. Time-resolved IR Absorption, spectroelectrochemistry, and TD-DFT calculations of fac-[Re(Cl)(CO)3(5-nitro-1,10-phenanthroline)]. J Phys Chem A vol. 109, (28) 6147-6153.
Blanco Rodríguez AM, Gabrielsson A, Motevalli M et al.(2005). Ligand-to-diimine/metal-to-diimine charge-transfer excited states of [Re(NCS)(CO)3(alpha-diimine)] (alpha-diimine = 2,2'-bipyridine, di-iPr-N,N-1,4-diazabutadiene). A spectroscopic and computational study. J Phys Chem A vol. 109, (23) 5016-5025.
Busby M, Matousek P, Towrie M et al.(2005). Ultrafast excited-state dynamics preceding a ligand trans-cis isomerization of fac-[Re(Cl)(CO)(3)(t-4-styrylpyridine)(2)] and fac-[Re(t-4-styrylpyridine)(CO)(3)(2,2 ' bipyridine)](+). J PHYS CHEM A vol. 109, (13) 3000-3008.
Towrie M, Gabrielsson A, Matousek P et al.(2005). A high-sensitivity femtosecond to microsecond time-resolved infrared vibrational spectrometer. Appl Spectrosc vol. 59, (4) 467-473.
Vlcek A, Zális S(2005). Comments on "Theoretical studies of ground and excited electronic states in a series of halide rhenium(I) bipyridine complexes". J Phys Chem A vol. 109, (12) 2991-2992.
Gabrielsson A, Zális S, Matousek P et al.(2004). Ultrafast photochemical dissociation of an equatorial CO ligand from trans(X,X)-[Ru(X)2(CO)2(bpy)] (X = Cl, Br, I): a picosecond time-resolved infrared spectroscopic and DFT computational study. Inorg Chem vol. 43, (23) 7380-7388.
Busby M, Gabrielsson A, Matousek P et al.(2004). Excited-state dynamics of fac-[ReI(L)(CO)3(phen)]+ and fac-[ReI(L)(CO)3(5-NO2-phen)]+ (L = imidazole, 4-ethylpyridine; phen = 1,10-phenanthroline) complexes. Inorg Chem vol. 43, (16) 4994-5002.
Busby M, Matousek P, Towrie M et al.(2004). Rhenium-to-benzoylpyridine and rhenium-to-bipyridine MLCT excited states of fac-[Re(Cl)(4-benzoylpyridine)(2)(CO)(3)] and fac-[Re(4-benzoylpyridine)(CO)(3)(bpy)](+): a time-resolved spectroscopic and spectroelectrochemical study. Inorg Chem vol. 43, (14) 4523-4530.
Liard DJ, Busby M, Matousek P et al.(2004). Picosecond relaxation of (MLCT)-M-3 excited states of [Re(Etpy)(CO)(3)(dmb)](+) and [Re(Cl)(CO)(3)(bpy)] as revealed by time-resolved resonance raman, UV-vis, and IR absorption spectroscopy. J PHYS CHEM A vol. 108, (13) 2363-2369.
Zális S, Busby M, Kotrba T et al.(2004). Excited-state characters and dynamics of [W(CO)(5)(4-cyanopyridine)] and [W(CO)(5)(piperidine)] studied by picosecond time-resolved IR and resonance Raman spectroscopy and DFT calculations: roles of W --> L and W --> CO MLCT and LF excited states revised. Inorg Chem vol. 43, (5) 1723-1734.
Liard DJ, Busby M, Farrell IR et al.(2004). Mechanism and dynamics of interligand electron transfer in fac-[Re(MQ(+))(CO)(3)(dmb)](2+). An ultrafast time-resolved visible and IR absorption, resonance raman, and emission study (dmb = 4,4 '-dimethyl-2,2 '-bipyridine, MQ(+) = N-methyl-4,4 '-bipyridinium). J PHYS CHEM A vol. 108, (4) 556-567.
Busby M, Liard DJ, Motevalli M et al.(2004). Molecular structures of electron-transfer active complexes [Re(XQ(+))(CO)(3)(NN)](2+) (XQ(+) N-Me-4,4 '-bipyridinium or N-Ph-4,4 '-bipyridinium; NN = bpy, 4,4 '-Me-2-2,2 '-bpy or N,N '-bis-isopropyl-1,4-diazabutadiene) in the solid state and solution: an X-ray and NOESY NMR study. INORG CHIM ACTA vol. 357, (1) 167-176.
Liard DJ, Kleverlaan CJ, Vlcek A(2003). Solvent-dependent dynamics of the MQ*-->ReII excited-state electron transfer in [Re(MQ+)(CO)3(dmb)]2+. Inorg Chem vol. 42, (24) 7995-8002.
Zalis S, Farrell IR, Vlcek A(2003). The involvement of metal-to-CO charge transfer and ligand-field excited states in the spectroscopy and photochemistry of mixed-ligand metal carbonyls. A theoretical and spectroscopic study of [W(CO)(4)(1,2-ethylenediamine)] and [W(CO)(4)(N,/N '-bis-alkyl-1,4-diazabutadiene)]. J AM CHEM SOC vol. 125, (15) 4580-4592.
Zalis S, VLCEK A, Daniel C(2003). The character of low-lying excited states of mixed-ligand metal carbonyls. TD-DFT and CASSCF/CASPT2 study of [W(CO)(4)L] (L = ethylenediamine, N,N '-dialkyl-1,4-diazabutadiene) and [W(CO)(5)L] (L = pyridine, 4-cyanopyridine). Czechoslov. Chem. Commun. vol. 68, (1) 89-104.
Farrell IR, Matousek P, Towrie M et al.(2002). Direct observation of competitive ultrafast CO dissociation and relaxation of an MLCT excited state: picosecond time-resolved infrared spectroscopic study of [Cr(CO)(4)(2,2'-bipyridine)]. Inorg Chem vol. 41, (17) 4318-4323.
Vlcek A(2002). Highlights of the spectroscopy, photochemistry and electrochemistry of [M(CO)(4)(alpha-diimine)] complexes, M=Cr, Mo, W. COORDIN CHEM REV vol. 230, (1-2) 225-242.
Vlcek A(2002). Preface. COORDIN CHEM REV vol. 230, (1-2) 1-1.
Vlcek A, Farrell IR, Liard DJ et al. (2002). Early photochemical dynamics of organometallic compounds studied by ultrafast time-resolved spectroscopic techniques. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS. 701-712.
Turki M, Daniel C, Zalis S et al.(2001). UV-visible absorption spectra of [Ru(E)(E ')(CO)(2)(iPr-DAB)] (E = E ' = SnPh3 or Cl; E = SnPh3 or Cl, E ' = CH3; iPr-DAB = N,N '-di-isopropyl-1,4-diaza-1,3-butadiene): Combination of CASSCF/CASPT2 and TD-DFT calculations. J AM CHEM SOC vol. 123, (46) 11431-11440.
Farrell IR, Hartl F, Zalis S et al.(2001). Electrochemical oxidation of [Cr(CO)(4)(tmp)] to the low-spin Cr(I) species [Cr(CO)(4)(tmp)](+) (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): an IR, UV-Vis, and EPR spectroelectrochemical and DFT computational study of the accompanying changes in molecular and electronic structure. INORG CHIM ACTA vol. 318, (1-2) 143-151.
Farrell IR, van Slageren J, Zalis S et al.(2001). Time-resolved emission spectra and TD-DFT excited-state calculations of [W(CO)(4)(1,10-phenanthroline)] and [W(CO)(4)(3,4,7,8-tetramethyl-1,10-phenanthroline)]. INORG CHIM ACTA vol. 315, (1) 44-52.
Guillaumont D, Vlcek A, Daniel C(2001). Photoreactivity of Cr(CO)(4)(2,2 '-bipyridine): Quantum chemistry and photodissociation dynamics. J PHYS CHEM A vol. 105, (7) 1107-1114.
VLCEK A(2001). Electron Transfer Processes in Mononuclear Polypyridine Metal Complexes. Electron Transfer in Chemistry, Editors: Balzani, V, vol. Vol 2, Wiley-VCH (Weinheim),
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